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Post by Arnie Benton on Aug 24, 2015 18:34:29 GMT -6
I've been feeling really good recently - 2 kiln loads - 25 pieces ALL came out "OK". But the last load - testing a new engobe (still trying to cut down crazing) was NOT OK. I decided to salvage what I could - and did a refire - adding a coating of a low Zinc glaze - Here are a couple of results - First Firing Refired - crazing gone And another - First Firing - lots of crazing - Refire - Crazing still there, so piece was struck - I do enjoy 'reclamation projects'. By the way, I have been using Silica Sand on my kiln shelves - just a light dusting - and haven't had any major cracks or breakage in the last 3 firings. I also stopped slowing down through the inversions so maybe the sand is really the 'answer'. Too soon to know. Arnie
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Post by mohawkpiper on Aug 24, 2015 19:59:53 GMT -6
Arnie, i really like BOTH the before AND after of the first equally. The second i like the refire best. I dont enjoy refiring stuff so they pile up until they just need to be done. We did a refire load yesterday and most stuff improved a good amount. Got a second load of refires in right now and hopefully results will be even better. Applying new glaze to an already fired piece is not easy.
It is pretty intersting how striking can "hide" the crazing isnt it?
G
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Post by Arnie Benton on Aug 24, 2015 21:28:10 GMT -6
Hi Greg - That's where horizontal surfaces are great - I brush a little glaze on, or just wet it with a little water and heat in microwave for a minute and then it's easy to put more glaze on the warm surface. Since many vertical pieces won't fit in a microwave, I'd heat in oven - but it's hard to fight gravity.
A suggestion was made a while back that striking makes pieces matte and the increased opaqueness hides the crazing - maybe, but the piece pictured above is as glossy as it was before striking. Striking also turns blue crystals gray. I'd love to figure that one out. I do wonder if it's from the background getting darker.
Arnie
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Post by mohawkpiper on Aug 24, 2015 22:52:17 GMT -6
haha yea flat is easier to reglaze i stick my stuff in the kiln and bring it to 285°F and let it soak a little then pull it out with gloves and start brushing, or spraying, and the glaze dries up instantly with this slurp sound. I put it back in for the second coat. thats where the glaze catchers come in handy cuz i can hold the piece by the catcher. we like our catchers to have a little hold to them for that reason. if they come off too easy they pop off in the reglaze or if theyve come off already you have nothing to hold onto I think the observation about matte and striking is correct, but under the right circumstances. each glaze is different, and the same glaze struck to different cones can be different. most of the stuff we strike stays glossy but i have gotten matte stuff in the past. arnie you have already figured it out. strike it and it will turn grey. reduction can also turn a blue crystal grey. again not always, but with the right circumstances. forgive my texting lingo... G
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timhanrahan
New Member
Still growing crystals!
Posts: 22
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Post by timhanrahan on Aug 27, 2015 8:12:09 GMT -6
Hi Guys,
The answer is probably in the bowels of the the old forum, but I'll ask again. My unscientific analysis is that most re-fires produce more and smaller crystals (same glaze). I would appreciate your thoughts on why this happens and approaches to avoid this, as re-fires are a fact of life, at least in my world.
Tim
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Post by Arnie Benton on Aug 27, 2015 9:48:08 GMT -6
Hi Tim - I do lots of refires - but only on plates and bowls, so anything I say applies only to horizontal surfaces - my experience is the same as yours. Refires always make lots of small crystals. Pieces with few or no crystals on first firing will make an OK # of crystals on refire, with nothing added or a normal zinc glaze, but still small. Pieces with lots of crystals on first firing come out overloaded with small crystals on refire. I put a glaze with lo zinc (about 12 to 14 gms) on the pieces with lots of crystals and get an OK number on refire, but still small - plus often interesting colors - the glaze I put on top may be CuCoTi or CoTi - sometimes a NICuFeTi glaze. I do find that Ti is important. Put a glaze with normal zinc on top and it comes out loaded with crystals. I think firing changes the glaze chemistry - from interaction with the clay body - I've often thought of refiring at a lower temp and or soaking at a lower temp since the piece has already had a lot of heat work - but have never done it. With horizontal surfaces all the glaze is still on the pot - no run off - with vertical surfaces with all the run off results are probably different.
For design purposes I sometimes lower the zinc in the first firing, knowing I'm going to refire - I have come to like the smaller, wilder crystals from refire, because I'm looking to make the ground more important - as you can see in the struck piece above - so I start out thinking I am going to fire, refire and either strike or lofire reduce. I can almost 'see' my pieces shudder at the thought of what they are going to be put through!
Arnie
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Post by mohawkpiper on Aug 27, 2015 13:05:02 GMT -6
Hi Tim,
Pam and I also do a lot of refires. Probably not anywhere near how many Arnie does though! We work mostly on vertical, and I don't have an explanation for any of it, but I think it just comes down to your glaze (composition and whatnot), and your initial thickness as well as the second applied thickness. Assuming same glaze and same peak temp.
We sorta get stuff all over. Sometimes a refire will cause many smaller crystals. (Mostly we found this with our red stained pieces.) With some tweaking of the glaze we were able to fix this and now refires pretty much come out the way we expect them initially (for that glaze specifically), albeit we haven't refired that one much.
Sometimes we get the opposite. Few crystals, and spiky-er but still kinda the same size. I believe this is due to initial thickness AND reapplied thickness. being too thick. This happens with our glazes that are a little pickier with thickness. (nickel mostly.) Ive tweaked the glaze to be more forgiving but it still isnt like most of the others. I believe when this happens its too thick overall (mostly on the reglaze) because the crystals are spiky-er with the same hold temps. At one hold temp you can get a variety of shapes just off glaze thickness. But sometimes with the same glaze we can refire and get what we expect. good coverage. so it's different sometimes for the same glaze even.
Most of our glazes are pretty forgiving and we can refire expecting the same results in crystal amount, size, and shape, as an initial firing. We mostly refire Pam's mugs since most of the glazes I haven't been able to rid entirely the different color in the bg at the top when the glaze thins and since her pieces are shorter than mine she gets more of that than I do. We both like the thicker colors at the bottom so she refires and they thicken up a little and she gets more of the color she wants. The one she finds this most with is the black glaze. That is the only one she almost fires with the intent of refiring because the first time around it usually has a lot more of the blue-ish color (though not always.) But that glaze the crystals almost always come out the same in an initial firing as they do in a refire.
We use mostly two types of clay and sometimes a third and I haven't noticed any difference between the clays but I haven't tested for it either.
When I say tweaking of the glaze to fix these issues I find it is mostly the colorants that need to be tweaked to fix it, which can be tricky sometimes to still achieve the color you want. less so tweaking of the base, but still that sometimes too.
have you tried a refired thickness test? fire a bunch of stuff in the same glaze (similar forms too). pick out three or four that all have similar results, then refire them, putting on a different amount of layers (or measured thicknesses, or grams per square inch, or however you do it) with one having no new glaze at all. see what happens.
G
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Post by tileman2 on Aug 27, 2015 16:46:36 GMT -6
Been following this refire, strike fire, and reduction fire postings for some time. Would like to make a suggestion: and that is data. Perhaps compile a database of information regarding temps, acid baths which include solution percentages and length of time. Was the piece rinsed or the acid neutralized before being subjected to a refire? Is there a definitive high end limit for temp before crystals begin to restructure?
MSDS sheets for all zinc state: "reactive to acid and alkaline (base)." Alkaline can have just as much of an effect as acid: reason for the long standing debate over acid and alkaline index in glaze formulation. Also the reason lithium is such an effective flux in this glaze: much more so than others. Getting ready to run a reduction test shortly, but am going to soak the test pieces in sodium hydroxide first: 13.4 PH (caustic level). Am already aware that iron, copper, and zinc react to caustic levels of alkaline; just as react to acids.
Lithium: 10.95 PH Calcium 8.9-9.2 PH Sodium and Potassium Feldpsars: 8.6-9.4 PH. HCL 20% 1.5PH The big problem with HCL is that it continues attacking metal oxides even after it has air dried. Neutralizing it with a rinse of very small amounts of calcium, feldspars, or even baking soda would stop that process. Porcelain clay runs about 8.8 PH because the basic ingredients are alkaline: which leaching HCL could partially break down if soaked for long periods-- IE - exploding pots in kiln.
Have other thoughts about reduction mediums: but will test those theories first. Just some thoughts.
Tom
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Post by Arnie Benton on Aug 28, 2015 10:36:18 GMT -6
I'm going to try reduction and striking after etching - but I haven't done that yet. My personal interest has been more in the area of refires, layered glazes, proportion of crystals to ground and striking and or lofire reduction. My frustration at the moment is the great difference that 1 gm of Zn makes in size and number of crystals. 21 gms is too much and 20 gms is too little - with the same firing schedule, glaze thickness, etc. I've gotten some nice results with etching and have struck few but no full refire. I haven't paid attention to pH, and am interested in your tests.
Arnie
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Post by tileman2 on Aug 28, 2015 15:46:15 GMT -6
Arnie ( and others interested )
This weekend I will fire a batch of test tiles with 3% rutile, and then 1 and 2% CU. Will soak one set in 20 HCL and another set in 13.4 potassium. Then I will leave one set plain. Then I will do a reduction firing on one set, and a strike on another; and just a refire on the plain set. Perhaps one hour of reduction at what temp? Suggestions for target temps? Missing anything in this test protocol?
Tom
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Post by Arnie Benton on Aug 28, 2015 16:01:22 GMT -6
Hi Tom - For post fire reduction I go up to 1350 - reduce for seven (7) minutes (!) and shut it off - and not too heavy a reduction. I started reducing for 90 minutes and through the years have kept lowering the time in reduction - am now down to 7 minutes and will be trying an even shorter time soon. Reds are much more likely to come out red - and not liver colored and blotchy. Two percent copper will probably change to the metal. I do striking to the same temp - 1350 - and hold for 90 minutes. How it all will react to acid or alkali I would like to know! Is Copper OK to use in a kitchen, given how easily it leaches out?
Arnie
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Post by sherri on Sept 13, 2015 17:37:24 GMT -6
Always intriguing to see your tests Dr. Arnie. Thank you
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